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THE BASICS OF ORGANIC CHEMISTRY |
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Carbon and hydrogen are the featured elements by definition in organic chemistry, but they are not the only players. But before getting to the others, some discussion about carbon's capabilities is necessary. For anyone who needs to "see" these examples, most of the links lead to visualizations. Simple hydrocarbons include methane, CH4, ethane, C2H6 (each carbon has a bond with the other, leaving 6 of the total 8 for hydrogens), and propane, C3H8. As the number of carbons grow, the arrangement of how the carbons connect and what parts are where can vary, producing isomers: molecules with the same basic formula that are put together differently. Stereoisomers are molecules that can differ in the rotation of single bonds, often forming "mirror images" of each other. This type of change is also called chirality when the difference is a single "twist" one way or the other. Complex hydrocarbons with the same atomic constituents can vary even with all of the atoms bound to the same neighbors, because the bonds themselves can be turned differently - these molecules would differ in three-dimensional arrangement or conformation. Also, similar molecules can differ in how carbons are bonded - when double bonds exist in a molecule, it is called unsaturated (there is room for more hydrogens), and if only single bonds exist between the carbons, the molecule is saturated, it has no more room for hydrogens on the carbons. Beyond "HONC," there are other elements that
are important constituents in living systems, but in much lower
amounts. Phosphorus, for example, is a critical part of
Adenosine
Triphosphate (ATP), the fuel molecule that supplies energy to cell
functions; Sulfur is often used to covalently cross-connect parts of
proteins more strongly than hydrogen bonds can; many metals function
as associates of important protein systems; ions have already been mentioned
as being important. |
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MANY MOLECULES HAVE THE SAME FUNCTIONAL GROUPS |
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There are several atom combinations that show up again and again in molecules and affect the chemistry of the molecules. All of these groups tend to be polar, and it is the polarity characteristics that help determine their chemistry: ALDEHYDE, -C=O on an end carbon. KETONE, -C=O on an internal carbon. CARBOXYLS, ACID GROUPS, -COOH. These will generally give up the hydrogen on the end as an ion, adding such H+ ions to solution, which is why it's an acid. AMINES / AMINO GROUPS, -NH2. These tend to pick up hydrogen ions from solution, making the solution basic. THIOLS (MERCAPTANS), -SH. When found inside large molecules, loses hydrogens and covalently bonds to other sulfurs, forming covalent internal bridge-like connections that can help to hold a molecule in a stable form.
PHOSPHATES, -POX.
Varies in form according to pH. Commonly moved onto and off
molecules as an energy carrier. |
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Online Introduction to Biology (Advanced)
Copyright 2003 - 2008, Michael McDarby.
Reproduction and/or dissemination without permission is prohibited. Linking to these pages is fine.